These Celebrity Couples Were All Married to Other People When They Met

Blake Shelton met Miranda Lambert in 2005 while he was married to Kanyette Williams, and she was engaged to Jeff Allen McManus. Both stars say they knew almost immediately that they had a connection.

Gwen Stefani and Blake Shelton met as judges on The Voice while he was married to Miranda Lambert and she was married to Gavin Rossdale. But in 2015, but stars filed for divorce within a month of one another.

Dwyane Wade and Gabrielle Union met in 2007 while co-hosting a Super Bowl party, while Wade was married to Siohvaughn Funches and Union was a year past her divorce from ex Chris Howard.

Jennifer Garner and Ben Affleck met in 2000 on the set of Pearl Harbor, when she was married to Scott Foley. But Affleck says it wasn’t until two years later, when they worked on Daredevil, that they fell in love.

Julia Roberts and Daniel Moder met while shooting The Mexican in 2000 — when Moder was still married to makeup artist Vera Steimberg, and Roberts was dating Benjamin Bratt.

Angelina Jolie met Brad Pitt on the set of Mr. and Mrs. Smith while he was married to Jennifer Aniston who filed for divorce in 2005.

John Travolta and Kelly Preston met in at a screen test for their upcoming film, 1989’s The Experts.

Megan Fox and Machine Gun Kelly first met in March 2020 filming Midnight in the Switchgrass, when Fox says she felt an instant electricity with Kelly despite her ongoing marriage to Brian Austin Green.

Read more about these celebrity couples who were married to other people when they met.